Origin of magnetically dead layers in spinel ferrites <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"><mml:mrow><mml:mi>M</mml:mi><mml:msub><mml:mi>Fe</mml:mi><mml:mn>2</mml:mn></mml:msub><mml:msub><mml:mi mathvariant="normal">O</mml:mi><mml:mn>4</mml:mn></mml:msub></mml:mrow></mml:math> grown on <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"><mml:mrow><mml:msub><mml:mi>Al</mml:mi><mml:mn>2</mml:mn></mml:msub><mml:msub><mml:mi mathvariant="normal">O</mml:mi><mml:mn>3</mml:mn…

نویسندگان

چکیده

We study the electronic and magnetic states of as-grown annealed $M\text{Fe}_2\text{O}_4$(111)/$\text{Al}_2\text{O}_3$(111) ($M=\text{Co, Ni}$) thin films with various thicknesses grown on Si(111) substrates $\gamma$-$\text{Al}_2\text{O}_3$(111) buffer layers by using x-ray absorption spectroscopy (XAS) circular dichroism (XMCD), to investigate magnetically dead in these films. Although samples are formed near interface $\text{Al}_2\text{O}_3$ layer, we reveal that ferrimagnetic order is partially recovered post-deposition annealing at 973 K for 48 hours air. By analyzing line shapes XAS XMCD spectra, conclude that, layers, there a significant number vacancies $T_d$ sites spinel structure, which may be microscopic origin degraded $M\text{Fe}_2\text{O}_4$(111)

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ژورنال

عنوان ژورنال: Physical Review Materials

سال: 2023

ISSN: ['2476-0455', '2475-9953']

DOI: https://doi.org/10.1103/physrevmaterials.7.044413